ORIGINAL_ARTICLE
Acetic Acid Catalyzed Synthesis of Benzo[h]quinazoline-2(3H)-thione Derivatives Using Polyethylene glycol--400 as Green Reaction Medium
In this present investigation, an efficient protocol for the synthesis of bundle of novel substituted benzo[h]quinazoline-2(3H)-thione derivatives was reported. The acetic acid catalyzed benzo[h]quinazoline-2(3H)-thione derivatives were prepared from 2-(substituted arylidene)-1-tetralones, thiourea and green solvent polyethylene glycol-400 with efficient and milder reaction condition. All the novel scaffolds were confirmed by the spectroscopic methods (IR, 1H NMR, Mass and Elemental analysis). The superiority of present method was operational simplicity, easy purification; high yields, easy available catalyst, environmental friendly solvent.
https://jaoc.samipubco.com/article_143904_1d671d6154c9002fddce351a63b2bf9f.pdf
2022-01-01
1
6
10.22034/jaoc.2022.319818.1042
acetic acid
PEG-400
Arylidene-1-tetralones
Thiourea
Benzo[h]quinazoline- 2(3H)-thiones
Green reaction solvent
Sadashiv
Nagre
sadashivnagre@gmail.com
1
Department of Chemistry, K. J. Somaiya College, Kopargaon-423601, (M.S.), India
AUTHOR
Namdeo
Dhokale
namdeo.dhokale@gmail.com
2
Department of Chemistry, K. J. Somaiya College, Kopargaon-423601, (M.S.), India
AUTHOR
Navnath
Dalvi
nrdalvi9595@gmail.com
3
Department of Chemistry, K. J. Somaiya College, Kopargaon-423601, (M.S.), India
AUTHOR
Satish
Kale
sbkale59@rediffmail.com
4
Department of Chemistry, K. J. Somaiya College, Kopargaon-423601, (M.S.), India
AUTHOR
Shankaraiah
Konda
kondasg@rediffmail.com
5
Department of Chemistry, K. J. Somaiya College, Kopargaon-423601, (M.S.), India
LEAD_AUTHOR
ORIGINAL_ARTICLE
Ammonium Chloride Catalyzed Green Synthesis, Characterization of Substituted 1-H-Indazole Derivatives
We have demonstrated novel and eco-friendly acceptable green methods for the synthesis of numerous 1-H-indazole by grinding protocol using NH4Cl milder acids in an EtOH solvent. The substituted 1-H-indazole synthesized from the grinding of ortho-hydroxybenzaldehyde with hydrazine hydrate in an Ethanol solvent and NH4Cl milder acids. The methods give good yield within less time. The protocol is practically green, milder, higher yield, with short reaction times.
https://jaoc.samipubco.com/article_144392_7e6e9fd9b71d552be5cf6e9f37349564.pdf
2022-01-01
7
14
10.22034/jaoc.2022.324460.1045
1-H-indazole EtOH
Hydrazine hydrate
NH4Cl
Grinding
Milind
Gaikwad
mvgaikwad76@gmail.com
1
Department of Chemistry, Dr. D. Y. Patil Arts Commerce and Science College Pimpri Pune -411018, India
LEAD_AUTHOR
Ravina
Jadhav
ravinajadhav307@gmail.com
2
Department of Chemistry, Dr. D. Y. Patil ACS Woman's College, Pimpri Pune-411018, India
AUTHOR
Monika
Dalvi
monikavd7786@gmail.com
3
Department of Chemistry, Dr. D. Y. Patil ACS Woman's College, Pimpri Pune-411018, India
AUTHOR
Anil
Nagane
avnagane@gmail.com
4
Telang Senior College of Arts, Science and Commerce, Nigdi, Pune-411044, India
AUTHOR
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ORIGINAL_ARTICLE
Meglumine Catalysed Green Synthesis of Ethyl-6-amino-5-cyano-2-methyl-4-phenyl-4H-pyran-3-carboxylate Derivatives
An efficient and simple one-pot synthetic protocol has been developed for the first time to synthesize the series of Ethyl-6-amino-5-cyano-2-methyl-4-phenyl-4H-pyran-3-carboxylates. This was achieved by the cyclocondensation of aromatic aldehydes, malononitrile, and ethylacetoacetate in the presence of the catalytic amount of Maglumine as a readily available, reusable, and biodegradable catalyst. This technique is very promising asit provides mild reaction conditions, an environmentally benign greener approach, easy workup process, high yield, less reaction time, low cost, and recycled up to five catalytic cycles without substantial loss of catalytic activity or product yield.
https://jaoc.samipubco.com/article_145841_1a1a4ea85831950cb62895f571bcbcf2.pdf
2022-01-01
15
23
10.22034/jaoc.2022.324493.1046
Meglumine
Recyclable
Ethyl-6-amino-5-cyano-2-methyl-4-phenyl-4H-pyran-3-carboxylates
Reusable
Cyclocondensation
Ganesh
Pund
ganeshpund2@gmail.com
1
Department of Chemistry, Dr. Rafiq Zakariya College For Women, Aurangabad (MS) India- 431001
AUTHOR
Sambhaji
Dhumal
sambhajirajedhumal@gmail.com
2
Department of Chemistry, Ramkrishna ParamhansaMahavidyalaya, Osmanabad (MS) India- 431501
AUTHOR
Madhav
Hebade
mjhebade@gmail.com
3
Department of Chemistry, Badrinarayan Barwale Mahavidyalaya, Jalna (MS) India- 431213
AUTHOR
Mazahar
Farooqui
mazahar_64@rediffmail.com
4
Department of Chemistry, Maulana Azad College of Arts Science and Commerce, Aurangabad, (MS) India- 431001
AUTHOR
Bhagwansing
Dobhal
drbsdobhal@gmail.com
5
Department of Chemistry, Badrinarayan Barwale Mahavidyalaya, Jalna (MS) India- 431213
LEAD_AUTHOR
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ORIGINAL_ARTICLE
Simple, Highly Efficient Synthesis 2-Amino-4-phenyl-4,5,6,7-tetrahydropyrano[3,2-c]carbazole-3-carbonitrile Derivatives Using Silica Supported Dodeca-Tungstophosphoric Acid DTP/SiO2
The one-pot multicomponent efficient and easily operational protocol has been developed for the synthesis of tetrahydropyrano[2,3-c]pyrazole-5-carbonitrile derivatives. The methods work via the multicomponent reaction between 5-methyl-2-phenyl-2,4-dihydro-3H-pyrazol-3-one , aldehyde and malononitrile catalyzed by the silica-supported dodeca tungstophosphoric acid (DTP/SiO2) catalyst. The protocol is practically green, milder reaction condition, higher yield, with short reaction times and recyclability of the catalyst.
https://jaoc.samipubco.com/article_147379_0168eba37367b69aa9872298d7a292e8.pdf
2022-01-01
24
30
10.22034/jaoc.2022.332760.1049
DTP/SiO2
Greener solvent
one-pot multicomponant
carbazole-3-carbonitrile
Sunil
Gaikwad
sunilunipune2012@gmail.com
1
Department of Chemistry, Dr. D. Y. Patil ACS Womens College, Pimpri, Pune-411014; Savitribai Phule Pune University, Pune, India
LEAD_AUTHOR
Murali Venkata
Basavanag Unnamatla
muralivenkat@ugto.mx
2
Centro Conjunto de Investigación en Química Sustentable UAEM-UNAM. Carretera Toluca-Atlacomulco Km 14.5, Toluca, Estado de México, 50200, México. Universidad Autónoma del Estado de México
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ORIGINAL_ARTICLE
Bi(OTf)3 as a Highly Potent Catalyst for the Synthesis of Mannich Bases under Milder Conditions
A simple, eco-friendly friendly and efficient procedure for the synthesis of Mannich Baseshas been developed via multi-component and one-pot reactions of various aldehydes with aniline, and acetophenone and catalytic amount of Bi(OTf)3 reagent in a DCM solvent.The Bi(OTf)3 acts as a highly potent catalyst ( 0.5 to 1 mol%) for a for the synthesis of Mannich base (1,3-diphenyl-3-(phenylamino)propan-1-one). This protocol is also compatible with a variety of hetero aldehyde carbonyl compounds in excellent yields. Thus, this practical method is developed as a notable medium for these derivatives via a multicomponent reaction.
https://jaoc.samipubco.com/article_149115_b3d6a4de90a80ab99ac3349415a5681c.pdf
2022-01-01
31
38
10.22034/jaoc.2022.336265.1052
Bi(OTf)3
one-pot three-component
greener
Mannich reaction
Somnath
Udgire
somnathudgire98@gmail.com
1
Dr. Arvind B. Telang Senior College of Arts, Science and Commerce, Pradhikaran Nigdi, Pune – 411044, India
AUTHOR
Milind
Gaikwad
mvgaikwad76@gmail.com
2
Department of Chemistry, Dr. D Y Patil ACS College Pimpri Pune; 411018, Affiliated to Savitribai Phule Pune University, Pune, India
AUTHOR
Prakash
Patil
pdp1111@gmail.com
3
Dr. Arvind B. Telang Senior College of Arts, Science and Commerce, Pradhikaran Nigdi, Pune – 411044, India
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ORIGINAL_ARTICLE
Isolation and Characterization of Bis(2-ethylheptyl) phthalate from Cynodon dactylon (L.) and Studies on Catalytic Activity of Its Cu(II) Complex in the Green Preparation of 1,8-Dioxo-octahydroxanthenes
Bis(2-ethylheptyl) phthalate is an anti-oxidant and anticancer compound that was extracted from the Cynodon dactylon plant stem extract and fully identified and characterized by FTIR, CHN, 1HNMR, 13CNMR, along with various 2D NMR techniques. The phthalate compound was modified and functionalized by polyethylene glycol (PEG) chains followed by complexation to Cu(II) ions. The resultant complex was applied as an efficient and strong recyclable homogeneous catalyst for the preparation of 1,8-dioxo-octahydroxanthenes under mild conditions. The homogeneous catalyst could be recovered and reused for several times.
https://jaoc.samipubco.com/article_149417_3a16f678eb2717d5837ac49b51a11409.pdf
2022-03-27
39
53
10.22034/jaoc.2022.149417
Xanthene
Copper complex
Trans-esterification
Homogeneous catalyst
Ali
Allahresani
a_allahresani@birjand.ac.ir
1
Department of Chemistry, Faculty of Science, University of Birjand, P.O. BOX 97175-615, Birjand, Iran
LEAD_AUTHOR
Fatemeh
Ghorbanian
f7272@yahoo.com
2
Department of Chemistry, Faculty of Science, University of Birjand, P.O. BOX 97175-615, Birjand, Iran
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Mohammad Ali
Nasseri
manaseri@gmail.com
3
Department of Chemistry, Faculty of Science, University of Birjand, P.O. BOX 97175-615, Birjand, Iran
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Milad
Kazemnejadi
miladkazemnejad@yahoo.com
4
Department of Chemistry, Faculty of Science, University of Birjand, P.O. BOX 97175-615, Birjand, Iran
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