Document Type : Original Article

Authors

1 Department of Chemistry, Lorestan University, Khorramabad 6813717133, Iran

2 Department of Chemistry, Lorestan University, Khorramabad Iran

Abstract

This reaserch aims at functionalizing magnetic mesoporous silica with methacrylic acid-3-aminopropyltriethoxysilane (Fe3O4@MCM-41@MAA-APTES) applied for removal of methylene blue from aqueous solution. Several variables (such as pH, dye concentration, adsorbent amount and contact time) have been investigated. Under optimum conditions, maximum capacity of 87.71 mg g-1 of MB was obtained for the sorbent. The magnetic mesoporous silica was characterized by SEM, FT-IR, XRD and VSM analyses. The adsorption isotherms were also studied for the sorbent and Langmuir model was found to be more applicable in interpreting MB adsorption on the magnetic nanocomposite silica. The pseudo-second order kinetic model adequately described the kinetic data.

Graphical Abstract

Novel modified magnetic mesopouros silica for rapid and efficient removal of methylene blue dye from aqueous media

Keywords

Main Subjects

 [1] J. Paul, K. Rawat, K. Sarma, S. Sabharwal, Appl. Radiat. Isot., 2011, 69, 982-987. ‎[Crossref], [Google Scholar], [Publisher]‎
[2] T. Pekdemir, B. Keskinler, E. Yildiz, G. Akay, J. Chem. Technol. Biot., 2003, 78, 773-780. [Crossref], [Google Scholar], [Publisher]
[3] E.J. Weber, V.C. Stickney, Water Res., 1993, 27, 63-67. ‎[Crossref], [Google Scholar], [Publisher]‎
[4] M.R. Mello, D. Phanon, G.Q. Silveira, P.L. Llewellyn, C.M. Ronconi, Micropor. Mesopor. Mat., 2011, 143, 174-179. ‎[Crossref], [Google Scholar], [Publisher]‎
[5] T. Robinson, G. McMullan, R. Marchant, P. Nigam, Bioresour. Technol., 2001, 77, 247-255. ‎[Crossref], [Google Scholar], [Publisher]‎
[6] Z. Aksu, Process Biochem., 2005, 40, 997-1026. ‎[Crossref], [Google Scholar], [Publisher]‎
[7] M. El Haddad, R. Slimani, R. Mamouni, S. ElAntri, S. Lazar, J. Assoc. Arab Univ. Basic Appl. Sci., 2013, 14, 51-59. ‎[Crossref], [Google Scholar], [Publisher]‎
[8] H. Wang, X. Yuan, G. Zeng, L. Leng, X. Peng, K. Liao, L. Peng, Z. Xiao, Environ. Sci. Pollut. Res. Int., 2014, 21, 11552-11564. ‎[Crossref], [Google Scholar], [Publisher]‎
[9] C.K. Araújo, G.R. Oliveira, N.S. Fernandes, C.L. Zanta, S.S.L. Castro, D.R. da Silva, C.A. Environ. Sci. Pollut. Res., 2014, 21, 9777-9784. ‎[Crossref], [Google Scholar], [Publisher]‎
[10] E. Forgacs, T. Cserhati, G. Oros, Environ. Int., 2004, 30, 953-971. ‎[Crossref], [Google Scholar], [Publisher]‎
[11] E.C. Lima, B. Royer, J.C. Vaghetti, N.M. Simon, B.M. da Cunha, F.A. Pavan, E.V. Benvenutti, R. Cataluña-Veses, C. Airoldi, J. Hazard. Mater., 2008, 155, 536-550. ‎[Crossref], [Google Scholar], [Publisher]‎
[12] P.K. Malik, J. Hazard. Mater., 2004, 113, 81-88. ‎[Crossref], [Google Scholar], [Publisher]‎
[13] M. Hua, S. Zhang, B. Pan, W. Zhang, L. Lv, Q. Zhang, J. Hazard. Mater., 2012, 211, 317-331. ‎[Crossref], [Google Scholar], [Publisher]‎
[14] F. Han, V.S.R. Kambala, M. Srinivasan, D. Rajarathnam, R. Naidu, Appl. Catal. A-Gen., 2009, 359, 25-40. ‎[Crossref], [Google Scholar], [Publisher]‎
[15] V. Gupta, P. Carrott, M. Ribeiro Carrott, Suhas, Crit. Rev. Env. Sci. Tec., 2009, 39, 783-842. ‎[Crossref], [Google Scholar], [Publisher]‎
[16] P. Xu, G.M. Zeng, D.L. Huang, C.L. Feng, S. Hu, M.H. Zhao, C. Lai, Z. Wei, C. Huang, G.X. Xie, Sci. Total Environ., 2012, 424, 1-10. ‎[Crossref], [Google Scholar], [Publisher]‎
[17] S. Zhang, H. Niu, Z. Hu, Y. Cai, Y. Shi, J. Chromatogr. A, 2010, 1217, 4757-4764. ‎[Crossref], [Google Scholar], [Publisher]‎
[18] X. Zhao, J. Wang, F. Wu, T. Wang, Y. Cai, Y. Shi, G. Jiang, J. Hazard. Mater., 2010, 173, 102-109. ‎[Crossref], [Google Scholar], [Publisher]‎
[19] L.H. Luo, Q.M. Feng, W.Q. Wang, B.L. Zhang, Fe3O4/Rectorite composite: preparation, characterization and absorption properties from contaminant contained in aqueous solution, in:  Advanced Materials Research, Trans Tech Publ, 2011, pp. 592-598. ‎[Crossref], [Google Scholar], [Publisher]‎
[20] A. Çıtak, B. Erdem, S. Erdem, R.M. Öksüzoğlu, J. Colloid Interf. Sci., 2012, 369, 160-163. ‎[Crossref], [Google Scholar], [Publisher]‎
[21] S. Rostami, S.N. Azizi, N. Asemi, Iran. Chem. Commun., 2019, 7, 20-42. ‎[Crossref], [Google Scholar], [Publisher]‎
[22] B. Khodavirdilo, N. Samadi, R. Ansari, Iran. Chem. Commun., 2019, 7, 71-78. ‎[Crossref], [Google Scholar], [Publisher]‎
[23] T. Yokoi, Y. Kubota, T. Tatsumi, Appl. Catal. A-Gen., 2012, 421, 14-37. ‎[Crossref], [Google Scholar], [Publisher]‎
[24] H. Yan, M. Wang, Y. Han, F. Qiao, K.H. Row, J. Chromatogr. A, 2014, 1346, 16-24. ‎[Crossref], [Google Scholar], [Publisher]‎
[25] E. Tahmasebi, Y. Yamini, S. Seidi, M. Rezazadeh, J. Chromatogr. A, 2013, 1314, 15-23. ‎[Crossref], [Google Scholar], [Publisher]‎
[26] W. Stöber, A. Fink, E. Bohn, J. Colloid Interf. Sci., 1968, 26, 62-69. ‎[Crossref], [Google Scholar], [Publisher]‎
[27] E. Khaledyan, K. Alizadeh, Y. Mansourpanah, Iran. J. Sci. Technol. Trans. A: Sci., 2019, 43, 801-811. ‎[Crossref], [Google Scholar], [Publisher]‎
[28] K. Alizadeh, E. Khaledyan, Y. Mansourpanah, J. Water Environ. Nanotechnol., 2018, 3, 243-253. ‎[Crossref], [Google Scholar], [Publisher]‎
[29] W.J. Weber, J.C. Morris, J. Sanit. Eng. Div., 1963, 89, 31-60. ‎[Crossref], [Google Scholar], [Publisher]‎
[30] I. Langmuir, J. Am. Chem. Soc., 1916, 38, 2221-2295. ‎[Crossref], [Google Scholar], [Publisher]‎
[31] M. Mansour, M. Ossman, H. Farag, Desalination, 2011, 272, 301-305. ‎[Crossref], [Google Scholar], [Publisher]‎
[32] Y.-S. Ho, G. McKay, Process Saf. Environ. Prot., 1998, 76, 183-191. ‎[Crossref], [Google Scholar], [Publisher]‎
 [33] M. Ghaedi, A. Ghaedi, E. Negintaji, A. Ansari, A. Vafaei, M. Rajabi, J. Ind. Eng. Chem., 2014, 20, 1793-1803. ‎[Crossref], [Google Scholar], [Publisher]‎
[34] A. Asfaram, M. Ghaedi, S. Hajati, M. Rezaeinejad, A. Goudarzi, M.K. Purkait, J. Taiwan Inst. Chem. Eng., 2015, 53, 80-91. ‎[Crossref], [Google Scholar], [Publisher]‎
[35] M. Roosta, M. Ghaedi, A. Daneshfar, R. Sahraei, A. Asghari, Ultrason. Sonochem., 2014, 21, 242-252. ‎[Crossref], [Google Scholar], [Publisher]‎
[36] M. Ghaedi, A. Ghaedi, M. Hossainpour, A. Ansari, M. Habibi, A. Asghari, J. Ind. Eng. Chem., 2014, 20, 1641-1649. ‎[Crossref], [Google Scholar], [Publisher]‎
[37] Q. Zhou, Q. Gao, W. Luo, C. Yan, Z. Ji, P. Duan, Colloids Surf. Physicochemical Eng. Aspects, 2015, 470, 248-257. ‎[Crossref], [Google Scholar], [Publisher]‎
[38] D. Dutta, D. Thakur, D. Bahadur, Chem. Eng. J., 2015, 281, 482-490.[Crossref], [Google Scholar], [Publisher]‎